Agrochemical Intermediate Triazinamide for Piercing-Sucking Insecticide Production
1. Product Basic Identity
- Chemical Name: 4-Acetamido-6-methyl-1,2,4-triazin-3(2H)-one
- Alias: P4 Intermediate, Triazinamide
- CAS No.: 136738-23-3
- Molecular Formula: C6H10N4O2
- Appearance: White crystalline powder, low dust, stable storage
- Core Position: Exclusive upstream key intermediate for industrial production of Pymetrozine TC
2. Pymetrozine: Target Insecticide Against Piercing-Sucking Pests
Pymetrozine is a selective systemic feeding-blocking insecticide classified IRAC Group 9B, uniquely targeting homopteran piercing-sucking pests:
- Main controlled pests: Rice planthoppers, aphids, whiteflies, leafhoppers, thrips
- Application crops: Rice, wheat, vegetables, cotton, fruit trees
- Unique mode of action: Blocks insect stylet feeding instantly; pests stop nutrient intake irreversibly and starve to death within 48h; low toxicity to pollinators, no cross-resistance with neonicotinoids or pyrethroids
- Advantages: Strong systemic absorption, long residual efficacy, eco-friendly for integrated pest management (IPM)
3. Triazinamide’s Irreplaceable Synthetic Role
The whole industrial synthesis chain relies on Triazinamide to construct the triazinone core scaffold of Pymetrozine:
- Controlled deacetylation to form core amino-triazinoneIts acetyl protective group shields the triazine heterocycle from acid/thermal cleavage during hydrolysis. Mild deacetylation generates high-purity amino-triazinone without ring degradation or tar byproducts.
- High-yield condensation with nicotinaldehydeClean amino-triazinone derived from premium Triazinamide reacts selectively with nicotinaldehyde to cyclize into Pymetrozine, single-batch condensation yield above 92%. Ultra-low residual hydrazine impurities avoid wasteful hydrazone side reactions that consume costly nicotinaldehyde.
- Stable intermediate quality for continuous mass productionUniform crystal structure resists oxidation and premature hydrolysis during long-distance transport and bulk storage, eliminating batch fluctuation of finished insecticide technical material.
4. Premium Industrial Grade Specifications for Agro Manufacturing
- HPLC Purity: ≥99.0%
- Single unknown impurity: ≤0.15%
- Residual hydrazine, chloride, heavy metals strictly limited per global agrochemical raw material standards
- Moisture ≤0.3%, low insoluble impurities to prevent pipeline blockage in synthesis lines
5. Production & Environmental Benefits
- Boost total Pymetrozine production yield by 5%–8% vs crude unprotected triazine precursors
- Reduce solvent consumption and wastewater discharge by cutting repeated recrystallization cycles
- Minimize toxic byproducts, simplify waste treatment and meet international pesticide safety regulations
- Stable long-term stock capacity supports large-scale global agrochemical factory manufacturing
6. Packaging & Storage
25kg PE-lined fiber drums; seal tightly, store in cool, dry, dark warehouse, separate from strong acid, alkali and oxidants.